Targeted synthesis of a porous borazine-linked covalent organic framework.
نویسندگان
چکیده
The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SA(BET) = 1178 m(2) g(-1)) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol(-1).
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 70 شماره
صفحات -
تاریخ انتشار 2012